1003. ---------------. [Thermal Conversion of Ethylene and Ethane Into Other Hydrocarbons With Particular Regard to the Formation of Acetylene.] Brennstoff-Chem., vol. 13, 1932, p. 406-411, 435; Chem. Abs., vol. 27, 1933, p. 2016. Influence of time, distillation with H2, CH4, or N2, 2-stage treatment for liquid products, and partial combustion with O2 have been studied at high and low pressures for C2H4. Quantitative pure thermal dehydrogenation to C2H2 depends upon high temperature, a controlled brief time, low pressure, and distillation with H2. The dehydrogenation of C2H6 proceeds by stages, and yields of either 86% C2H2 or 72% C2H4 are obtainable by the control of similar factors as with C2H4. Includes brief review and bibliography. |