1000. ---------------. [Formation of Liquid Hydrocarbons From Acetylene.] Brennstoff-Chem., vol. 10, 1929, pp. 279-282; Chem. Abs., vol. 24, 1930, p. 483. Experimental method consisted in passing C2H2 over silica gel or active C at 600°-700°, the following results being obtained: With pure C2H2 at first CH4 and C were mainly formed, the latter serving as a contact whereby 70% of the C2H2 was converted into liquids (heavy oil : light oil = 1:1). With distilled C2H2 made by decomposing CH4 in coke-oven gas, the total conversion was smaller, but the light-oil yield was as high as with pure C2H2. Distillation with CO2 favored light oil formation and increased the life of the contact mass; CO2 could serve for revivifying the catalyst. With CO2-C2H2 mixtures in an empty tube, 70% of the C2H2 was converted into oil; reduced pressure was unfavorable. |