983. FISCHER, F., AND KOCH, H. [Chemism of the Benzine Synthesis and the Motor and Other Properties of Products Resulting Therefrom (Gas Oil, Benzine, Diesel Oil, Hard Paraffin).] Brennstoff-Chem., vol. 13, 1932, pp. 428-434; Ges. Abhandl. Kenntnis Kohle, vol. 11, 1934, pp. 516-530; British Chem. Abs., 1933, B, p. 50; Chem. Abs., vol. 27, 1933, p. 2017. Theories of hydrocarbon formation are discussed critically; the carbide theory of Fischer and Tropsch is believed most satisfactorily confirmed by experimental findings. Hydrocarbons higher than CH4 are obtainable from CO2-H2 mixtures only when the intermediate reduction to CO takes place. These are also obtained when HCOOH and MeOH are passed over Cu-Ni catalyst. Catalytic formation of paraffins of high melting point and molecular weight, composition, and characteristics of synthesis products, and their behavior as motor and diesel fuels have been investigated. Bibliography. |