935. FIRSANOVA, E. N. [Chemical Composition of Synthin. I.] Khim. Tverdogo Topliva, vol. 8, 1937, pp. 892-901; Chem. Zentralb., 1938, II, p. 1523; Chem. Abs., vol. 32, 1938, p. 4308. Products of the reaction of CO and H2 in the presence of the catalysts Ni-Al, Ni-Co-Si and catalyst “a” (composition not disclosed) at 180°-200° were analyzed. The mixture of gasoline and oil can yield a product boiling up to 200° in amounts of 60%. The synthin consisted mainly of paraffin hydrocarbons with smaller amounts of unsaturated compounds and no naphthenes nor aromatic compounds, therefore, the synthin had a low antiknock value. The residue boiling over 250° contained 57% of solid paraffin. n-C5H12, C6H14, C7H16, C8H18, C9H20, C10H22 and C11H24 were found in the paraffin-hydrocarbon fraction. Iso compounds were not found in the fractions boiling up to 200°. No cycloolefins nor diolefins were found. 12 refs. |