845. ERDMANN, E. Production of Methane From Carbon Monoxide and Hydrogen. Gas World, vol. 55, 1911, pp. 195-197; Jour. Gasbeleucht., vol. 54, 1911, pp. 737-741; Chem. Trade Jour., vol. 49, 1911, p. 175; Chem. Abs., vol. 5, 1911, pp. 3618, 3726. Commercial process (the Cedford gas process) is described of converting water gas into CH4 as follows: CO+3H2=CH4+H2O. In practice it is necessary to use 5 vol. H2 : 1 CO. A water gas containing 40% CO, 4% CO2, 52% H2, and 4% N2 after going through the process, contained traces of CO and CO2, 30% CH4, 62% H2 and 6-7% N2. The total cost was 8.5 d. per 1,000 cu. ft. |