828. EMMETT, P. H., AND CINES, M. Surface-Area Measurements on Metal Spheres and Carbon Blacks. Jour. Phys. and Colloid Chem., vol. 51, 1947, pp. 1329-1341; Chem. Abs., vol. 42, 1948, p. 1104. Comparison of areas obtained by adsorption isotherms for N2 at 195° on metal powders with those calculated from photomicrographs yields roughness factors in the range 1.1-1.8. Areas determined by the adsorption isotherms for CS2 and for C4H10 are 20-50% lower than those obtained by using N2 as adsorbate. Pelletizing carbon black produces no appreciable changes in its surface area per gm. |