744. DRAWE, R. [High-Heating-Value Gas From the Oxygen Gas Producer.] Gas- u. Wasserfach, vol. 76, 1933, pp. 541-545; Chem. Abs., vol. 27, 1933, p. 5172. At Tegel, brown coal was gasified at atmospheric pressure in an O2 gas producer at the rate of 200 kg. per m.2 producer area. Higher rates were not possible because of limited O2 supply. The O2 was saturated at 89°-93°. No slagging was noted. With O2 saturated at 90°, 1 m.3 O2 gave 16,000-17,000 cal. in the form of gas having the following analysis: CO2, 13.2%; O2, 1.1%; illuminants, 2.3%; CO, 32.9%; H2, 42.8%; CH4, 1.1%; and N2, 6.6%. 1 m.3 of O2 was enough to gasify 4 kg. brown-coal briquets. Experiments with an O2 gas producer at elevated pressures by the Lurgi Gesellschaft für Wärmetechnik were limited by the O2 supply to 900 kg. throughout per m.2 of producer area per hr. at an operating pressure of 20 atm. The back pressure with a 3-m. fuel bed was less than 50 mm. At the higher pressure tar oils and light oil were easily separated by cooling. The O2 used had a purity of 72-73%, but calculations as to O2 requirements were made on a basis of 90% O2, indicating that requirements per 4,000 cal. in the form of gas were 0.202 m.3 at 1 atm., 0.110 m.3 at 10 atm., and 0.80 m.3 at 20 atm. operating pressure. The calculated heating value of the CO2-free gases reached a maximum of 534 B.t.u. per cu. ft. at 20 atm., so that this gas should be satisfactory for city gas. An O2 price equivalent to about $0.10 per 1,000 cu. ft. is assumed in estimating that this gas could compete with other sources of city gas. |