712. DOLCH, P. [Action of Steam on Coal. Study of Superimposed Equilibria.] Ztschr. Elektrochem., vol. 38, 1932, pp. 596-601; British Chem. Abs., 1933, B, p. 5; Chem. Abs., vol. 26, 1932, p. 5193. Action of steam on coal leads to the formation of CO and H2. The formation of CO2 is a secondary reaction (CO+H2O=CO2+H2), the extent of which depends on the active coke surface. There is no evidence for the reaction C+2H2O=CO2+2H2. Experiments with CO2 and H2, which were passed over coke, confirm this. |