660. DANCKWERTS, P. V. Absorption by Simultaneous Diffusion and Chemical Reaction. Trans. Faraday Soc., vol. 46, 1950, pp. 300-304; Chem. Abs., vol. 44, 1950, p. 8706. Equations are derived for the rate of absorption and the concentration when a solute of limited solubility diffuses into a semi-infinite medium with which it undergoes a 1st-order reaction. Consideration is given to the case where the medium is a mixture only 1 component of which reacts. Examples are the absorption of a gas into a liquid or solid, the solution of a solid into a supernatant liquid, or the absorption of 1 solid or liquid material into another. |