635. CRANGLE, J., AND SUCKSMITH, W. Magnetic Analysis of Iron-Carbon Alloys. Tempering of Martensite and Retained Austenite. Jour. Iron Steel Inst. (London), vol. 168, 1951, pp. 141-151; Chem. Abs., vol. 45, 1951, p. 6559. Pure Fe-C alloys were austenitized and quenched to convert them to martensite. Magnetic analysis indicates that hexagonal Fe carbide is present in the 1st tempering stage (100° C.); its Curie point may be considerably lower than 380° C., and its composition may differ from Fe2C. The 2d tempering stage (150°-200° C.) is characterized by the absence of retained austenite (which decomposes into the same products that were formed in the 1st stage) and by the appearance, above 200° C., of a small amount of cementite. The shapes of the thermomagnetic curves of specimens in the 3d stage (250°-350° C.) suggest the presence of a carbide with properties similar to Hägg carbide. To eliminate this carbide completely, the temperature must be raised above 500° C, where the only remaining carbide is cementite. |