568. ---------------.[CHUFAROV, G. I., AND TATIEVSKAYA, E. P.] [Comparison of Initial Velocities of Reaction of Oxides of Iron With Hydrogen and Carbon Monoxide and Their Mixtures.] Jour. Phys. Chem. (U.S.S.R.), vol. 8, 1936, pp. 933-942; Chem. Abs., vol. 31, 1937, p. 2075. Near 500° the reduction of hematite is much slower by CO than by H2. At higher temperatures, 800°, the ratio of the velocities approaches the ratio of impinging molecules of the 2 gases. As a result of the smaller number of active centers at higher temperatures the absolute values of the reduction velocities are small. At 500° the presence of CO in mixtures of CO+H2 decreases the reduction below that expected for the partial pressure of H2, because of adsorption of CO on a large number of the active centers. |