560. CHRISTIANSEN, J. A. Equilibrium Between Methyl Formate and Methanol and Some Related Equilibria. Jour. Chem. Soc., 1926, pp. 413-421; Chem. Abs., vol. 20, 1926, p. 1745. For the reaction 2H2+HCO2Me=2MeOH, log KE=-(3.016/T)+3.61 (over a range of 180°-240°); MeOH+CO=HCO2Me, log10KE=-(1,880/T)+4.82. For these values the reaction CO+2H2=MeOH is calculated: log K3=-4,896/T+8.43. |