527. ---------------. [CHEMICAL INDUSTRIES.] From Wood Distillation to Oxo. Vol. 66, No. 6, 1950, p. 826. Tennessee Eastman Corp. has been producing a small amount of isobutyraldehyde as a byproduct from its Oxo pilot plant. A petrochemical plant is being constructed at Longview, Tex. The major product is to be n-butyric acid for the production of Tenite II, a cellulose acetate-butyrate plastic. The process to be used is a modification of the Oxo synthesis. Propylene (presumably produced by propane cracking) will be reacted with a mixture of CO and H2 to form a mixture of n-butyraldehyde and isobutyraldehyde. These will be fractionated, and oxidation of the latter compound will give n-butyric acid. |