524. ---------------.
[CHEMICAL INDUSTRIES.]
Separation
by Adsorption. Vol. 61, 1947, pp.
625-631; Fuel Abs., No. 3506, June 1948.
Summary of the development of adsorption as a method of separation is given with
reference to the production of activated C from bituminous coal, methods for the
activation of C, and hydrocarbon fractionation by means of fixed beds of C
attached to Fischer-Tropsch converters and operated in a manner similar to the
chromatographic separation of various components of solutions and by the
hypersorption process. The adsorbent C falls through a tower
countercurrently to hydrocarbon vapors. As the C falls, it adsorbs the
lighter constituents. Lower down the C meets with a greater concentration
of heavier constituents, which displace the lighter material. Thus,
throughout the length of the column, an effect is produced comparable to
refluxing in distillation. The bottom section consists of a steaming
section in which adsorbed material is stripped from the C. In a C2H4
recovery unit now in operation, 76,900 cu. ft. of gases containing 5.7% of C2H4
are fed into the tower per hr., and approximately 7,000 lb. of a product
containing 92% of C2H4 is obtained per day.
Activated C has been employed to recover antibiotics.
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