464. ---------------.[CHAKRAVARTY, K. M.] Catalytic Formation of Methane From Carbon Monoxide and Hydrogen. V. Study of the Promotor Effect on Nickel Catalyst. Jour. Indian Chem. Soc., vol. 15, 1938, pp. 245-248; Chem. Abs., vol. 32, 1938, p. 8742. Reduction of Ni catalyst at a temperature of 300° is incomplete when it is prepared from pure Ni acetate. Addition of a small quantity of a mixture of Ce nitrate and NH4 vanadate or of Ce nitrate and Cr acetate helps in bringing about a more thorough reduction. Thus catalysts of a reaction 2CO+2H2=CO2+CH4 is accelerated by these promoters through their influence on the preparation of the Ni. Whether the promoters have a direct effect on the reaction has not been settled. |