430. ---------------.[CANTELO, R. C.] Methane Equilibrium. III. Jour. Phys. Chem., vol. 31, 1927, pp. 246-250; Chem. Abs., vol. 21, 1927, p. 1583. In the catalytic decomposition of C2H4 the catalyst most effective is a specially prepared Ni-Ni oxide; at 300° and higher, CH4 is present in the products, the % of CH4 increasing with the temperature. C2H6 is stable up to 360° in the presence of a Ni catalyst. Equilibrium constants for the CH4 equilibrium at 500°-770° were obtained by repeatedly circulating the products of the catalytic decomposition of C2H4 over the Ni catalyst, which are in general agreement with those obtained by other investigators. |