427. ---------------.[CANTELO, R. C.] Thermal Decomposition of Methane. II. Jour. Phys. Chem., vol. 30, 1926, pp. 899-901; Chem. Abs., vol. 20, 1926, p. 2934. Equations for velocity of decomposition of CH4 to C and 2 H2 were derived and applied to experimental results at 985°. The reaction was only 36% complete after 1 hr. The velocity was abnormally high for 5 min. until the walls were covered with C. The velocity constant is of the order of 0.15. |