420a. CADY, W. E., LAUNER, P. J. AND WEITKAMP, A. W. Products of the Hydrogenation of Carbon Monoxide Over an Iron Catalyst. Aromatic Hydrocarbons. Am. Chem. Soc., 121st Meeting Abs., March-April, 1952, p. 10-M. Aromatics constitute about 6 wt. % of the hydrocarbons obtained in the hydrocarbon-synthesis process. They were separated by adsorption on silica gel and by distillation and were analyzed by ultraviolet and infrared spectroscopy. Benzene is present in traces, but successive C-number fractions contain increasing concentrations of aromatics. Monocyclic, cicyclic, and tricyclic aromatics occur in proportions that decrease with the number of aromatic rings. Some of the aromatic hydrocarbons contain a nonaromatic ring fused with the nucleus. Olefinic unsaturation is an important feature of the high-molecular-weight aromatics. Some unsaturation may be in the rings of compounds of the indene or the dihydronaphthalene series; the remainder is side-chain unsaturation. Aromatic rings occur to a small extent in the structures of the oxygenated compounds. In the benzene series, monoalkyl and o-dialkyl isomers predominate. A regular pattern of alkylbenzeneisomer distribution suggests a way in which the rings may have been formed. |