387. ------. [BRUNAUER, S., AND EMMETT, P. H.] Use of Low-Temperature van der Waals’ Adsorption Isotherms in Determining the Surface Areas of Various Adsorbents. Jour. Am. Chem. Soc., vol. 59, 1937, pp. 2682-2689; Chem. Abs., vol. 32, 1938, p. 1159. Van der Waals’ adsorption isotherms of some or all of the following gases were determined on a variety of adsorbents at the temperatures indicated: A and N2 at –195.8°; A, N2, CO, and O2 at –183°; CO2 at –78°; normal C4H10 and SO2 at 0°. The following adsorbents were used: 2 Cu catalysts, glaucosil, pumice, NiO supported on pumice, Ni on pumice, dry powdered bacteria, Cr2O3 gel, “glowed” Cr2O3, KCl, CuSO4·5H2O, CuSO4, 2 SiO2 gel samples, activated charcoal, and 2 Darco samples (activated carbons). All adsorbents except charcoal given sigmoid isotherms, and the values for the surface area evaluated from the different isotherms for the same adsorbent were consistent with one another. |