383. ------. [BRÜCKNER, H.] [Formation of Methane From Carbon Monoxide-Hydrogen Mixtures in Contact With Low-Temperature Coke at Increased Pressures.] Brennestoff-Chem., vol. 20, 1939, pp. 346-348; Chem. Abs., vol. 34, 1940, p. 7582. Conversion of H2 into CH4 in presence of low-temperature coke (5 gm. of coke, 1 liter of H2, standard conditions per hr., 50 atm.) rose from 7% at 500° to 23% at 700°. Correspondingly lower values were obtained at lower pressures. CH4 was also formed when a water gas was similarly treated; the reaction in this case, however, was principally 2CO+2H2=CH4+CO2. The maximum yield of CH4, 40% in the outlet gas, was obtained at 40 atm. and 700°; the yield fell with rising pressures. --------------. See abs. 408. |