374. ------. [BROWN, R. L., AND GALLOWAY, A. E.] Methanol From Hydrogen and Carbon Monoxide. II. Dimethyl Ether. Ind. Eng. Chem., vol. 21, 1929, pp. 310-313; Chem. Abs., vol. 23, 1929, p. 2150. Production of Me2O (I) as a side reaction of the synthesis of MeOH (II) over ZnCrO4 at 300°-400° and 180 atm. has been studied. The formation of I is slow and increases with temperature to 5.2% at 397° while II reaches a maximum of about 30% at 375° and then falls off. High space velocity favors formation of II. |