339. ---------------. [BREDIG, G., AND CARTER, S. R.] [Equilibrium of the Reduction of Carbonic Acid to Formic Acid.] Chem. Ztg., vol. 39, 1915, pp. 72-73; Chem. Abs., vol. 10, 1916, p. 1036. Considerable amounts of free HCOOH are obtained by the action of H2 and Pd black under pressure on CO2 in the presence of H2O; the HCOOH is decomposed catalytically into CO2 and H2. The determination of the equilibrium between these reactions between 30°-90° gave no indication of the formation of HCHO as an intermediate product, so that it is unlikely that the formation of the latter is a stage in the assimilation of CO2 in nature. |