331a. ---------------. [BRATZLER, K.] [Technical Production of Low-Boiling Hydrocarbons.] Erdöl u. Kohle, vol. 4, 1951, pp. 478-486; Fuel abs., vol. 10, No. 6, 1951, abs. 5,143. Processes for large-scale hydrocarbon production over past 30 hr. are chronologically briefly reviewed (decomposition of coke-oven gas, natural gas processes, high-pressure hydrogenation, Fischer-Tropsch synthesis, and various petroleum cracking processes). Details and flow sheets are given of processes for conversion of high-pressure hydrogenation waste gases to C4H10, C3H8, C2H6, and production of C2H4 from coke-oven gas. Descriptions and flow sheets are also given of batch production of gas oil and gasoline from Fischer-Tropsch waste gases and of continuous hypersorption and rectisorption processes. Disadvantages and operational difficulties of the various methods are discussed. BRAUDE, G., AND BRUNS, B. [Kinetics and Mechanism of the Catalytic Hydrogenation of Carbon Monoxide. II. Formation of Iron Carbide During Hydrogenation of Carbon Monoxide on an Iron Catalyst.] See abs. 333. |