310. BOTOLFSEN, E. [Studies of Catalysts.] Arch. Math. Naturvidensk., vol. B41, pt. 2, No. 7, 1938, p. 29. 1. Water-gas reaction. The effect of MgCO3 and MgO, alone and as carriers for other catalysts, on the course of the water-gas reaction is studied at temperatures 300°-800°. 2. CH4 formation in CO-steam mixtures. A catalyst obtained by precipitation from Ni nitrate solution forms CH4 from CO-H2O mixtures at temperatures at which formation of H2 does not yet occur. 3. Decomposition of CO in CO-steam mixtures. The catalyst described yields from this mixture a gas containing no CO. The reaction, separating out C, begins at 150° and is complete at 190°-195°. 4. Formic-acid formation in CO-steam mixture. HCOOH formation can be regarded as an intermediate stage of the water-gas reaction. 5. Ni carbonyl as catalyst. ---------------. See abs. 2583. |