301. BOOMER, E. H., AND MORRIS, H. E. Hydrogen-Carbon Dioxide Reaction. Jour. Am. Chem. Soc., vol. 54, 1932, p. 407; Chem. Abs., vol. 26, 1932, p. 1180. With an unsupported Zn-Cu-Al catalyst, a gas mixture of 27% CO2, 71% H2, and 2% N2 at 325° and 1,700 lb. pressure gave an effluent gas containing 4% CO. This suggests that the primary step in the synthesis of MeOH from CO2—H2 involves the reduction of CO2 and the nature of the catalyst determines the extent to which the resultant CO is hydrogenated. As the activity of the catalyst decreases the MeOH reaction is most affected; experiments with this same catalyst and water gas gave appreciable amounts of CO2. This suggests a new mechanism for the synthesis of MeOH, which will be discussed later. BOOMER, E. H., AND THOMAS, V. Oxidation of Methane at High Pressure. II. Experiments With Various Mixtures of Viking Natural Gas and Air. See abs. 299. ---------------. Oxidation of Methane at High Pressure. III. Experiments Using Pure Methane and Principally Copper as Catalyst. See abs. 300. |