284. BOEHM, E., AND BONHOEFFER, K. F. [Gaseous Reactions of Active Hydrogen.] Ztschr. Physial, Chem., vol. 119, 1926, pp. 385-399; Chem. Abs., vol. 20, 1926, p. 3645. Reactions of H2 activated by luminous discharge have been studied semiquantitatively for the following substances: O2, H2O, N2, NH3, Cl2, HCl, Br2 HBr, H2S, CH4, CO, CO2, and CH3Cl. The H2 behaves as though it consisted of free atoms; with O2 it forms directly H2O2, with CO and CO2 it forms small quantities of CH2O. The halogens, which react very rapidly, form H halides. The active form of H is rapidly and completely destroyed by HCl, HBr, H2S, and CH3Cl, probably because of reactions like H+HCl=H2+Cl. N2, H2O, NH3, and CH4 are indifferent. Small quantities of O2 increased the yield of active H2 as they also increase the intensity of the Balmer spectrum; but the other gases tried had no effect. |