282. BOCHAROVA, E. M., DOLGOV, B. N., KAN-KOGAN, K. I., AND PETROVA, Y. N. [Synthesis of Higher Alcohols From Carbon Dioxide and Hydrogen Under Pressure. V.] Khim. Tverdogo Topliva, vol. 8, 1937, pp. 1107-1121; Chem. Abs., vol. 32, 1938, p. 4518. This method was described previously. The synthesis was carried out at 350°-425° at a constant pressure of 220 atm. The previously described catalysts, 8ZnO.Al(OH)3O.1 V2O5.3KOH and 8ZnO.Al(OH)3.O.1 V2O3.O.1 MoO3. 3KOH used in the above synthesis yielded water 70%, MeOH 25%, and higher alcohol 5% by weight of the condensate. The best CO2:H2 ratio for the synthesis of higher alcohols than MeOH was 1:2.2. The yield of alcohol fraction boiling 70°-95° for the first catalyst was 266 cm.3/1. of catalyst/hr. Qualitative analysis of the condensate disclosed the presence of considerable amounts of MeOH and 5% of the zeotropic mixture of iso-PrOH, PrOH, and iso-BuOh. 17 refs. BOCHAROVA, E. M., DOLGOV, B. N., AND PETROVA, Y. N. [Synthesis of Higher Alcohols From Water Gas Under Pressure. II.] See abs. 279. BOCHAROVA, E. M., DOLGOV, B. N., AND PROKHOROVA, Z. M. [Synthesis of Higher Alcohols From Water Gas Under Pressure. III.] See abs. 280. BOCHAROVA, E. M., DOLGOV, B. N., AND KAN-KOGAN, K.I., AND PETROVA, Y. N. [Synthesis of Higher Alcohols From Carbon Dioxide and Hydrogen Under Pressure. V.] See abs. 282. BOCHAROVA, E. M., DOLGOV, B. N., PETROVA, Y. N., AND YATSKOVSKAYA, N. S. [Synthesis of Alcohols of High Molecular Weight From Water Gas Under Pressure. IV. Rechecking of the Methods for Analysis of the Condensate.] See abs. 281. BOCHIROI, L. See abs. 215. BODE, K. See abs. 2921. |