209. BERNIER, R., AND MICHEL, A. [Hexagonal Phase Appearing in Evolution of Fischer Nickel Catalyst.] Bull. Soc. Chim., France, 1948, p. 1073. Ni dispersed on ThO2 forms a hexagonal carbide during the synthesis with 6-7% C. The hexagonal close-packed structure has a=2.64 Å, c=4.32 Å, c/a=1.63. The paramagnetic carbide is destroyed in vacuo at 210° and forms a ferromagnetic face-centered cubic phase with Curie point=314°. |