206. -----------------. [ BERL, E., AND BEMMANN, R.] [Effect of Hydrogen on Charcoal and Active Carbon and the Methane Synthesis.] Ztschr. Physik. Chem., vol. A162, 1932, pp. 71-93; Chem. Abs., vol. 27, 1933, p. 223. Pressure hydrogenation of charcoal and activated C gives CH4 almost entirely. The thermodynamic equilibrium leads to certain conclusions on free energy of para-crystalline C. Natural C gives liquid hydrocarbons, but since charcoal and activated C give none of them, their structure must be fundamentally different. Presents views of the structure and reaction mechanism. |