177. --------------. [BEECK, O.] Surface Catalysis. Rev. Modern Phys., vol. 20, 1948, pp. 127-130; Chem. Abs., vol. 42, 1948, p. 4435. Review of work of Beeck and associates. The discovery of the effect of traces of H2O and H2S in lowering the decomposition temperature of hydrocarbons is discussed. The molecular-ray experiments also seem to indicate the decomposition of CH4 into CH3 and H and C2H6 into 2 CH radicals. There is evidence that the CH radical is formed in the decomposition of acetylene. The adsorption step is the crucial step in surface catalysis, and the reaction of ethylene and H2 is cited as an example. Finally the tracer technique is discussed in connection with the isomerization of butane to isobutane. |