165. BAUKLOH, W., AND HIEBER, G. [Influence of Various Metals and Metallic Oxides Upon Carbon Monoxide Decomposition.] Ztschr. anorg. Chem., vol. 226, 1936, pp. 321-332; Chem. Abs., vol. 30, 1936, p. 5139. Reaction 2CO=CO2+C was studied by passing CO gas over Fe2O3, Fe3O4, Fe, Co3O4, Co, Ni2O3, NiO, Ni, Cr2O3, Cr, Mn3O4, Mn, Al2O3, Al, ZnO, Zn, and Cu at 350° to 850°. The extent of the reaction is measured by weighing the C produced. The quantity of C separated rises to a maximum and then decreases, the maximum being at 550° for Fe and Fe oxides, at 650° for Co and Co oxides, at 450° for Ni oxides but at 750° for Ni, at 650° for Cr, and at 850° for Mn. No C separates with Mn3O4, Al2O3, Zn or ZnO, nor with CuO. It is concluded that not the oxides but metals produced from them cause the CO decomposition |