163. BAUKLOH, W., AND HELLBRÜGGE, J. [Effect of Some Substances on the Decomposition of Carbon Monoxide and Methane.] Arch. Eisenhüttenw., vol. 15, 1941, pp. 163-166; Brennstoff-Chem., vol. 23, 1942, p. 7; Chem. Abs., vol. 36, 1942, p. 7268. In the presence of catalysts, such as metallic Fe, and at certain temperatures, CO disintegrates forming free C. The velocity of decomposition depends on the nature of the catalysts and is greatest at temperatures between 500°-600°. Fe2O3 mixed with SiO2, CaO, Al2O3 or Cr2O3 caused a lowering in the catalytic decomposition of CO. Cr2O3 is the most effective. CH4 has no critical-decomposition region; at higher temperatures, however, it is more unstable than CO and decomposes with greater velocity. Mixtures of Fe2O3 with CdSO4, HgCl2 or B2O3 are equally good. |