151. BASHKIROV, A. N., AND CHERTKOV, I. B. [Oxidation of High-Molecular-Weight Synthetic Paraffin.] Bull. aca. sci. U.R.S.S., Sec. Tech. Sci., 1947, pp. 817-824. Paraffin obtained by the Fischer-Tropsch reaction (molecular weight, about 1,000) was oxidized with air in the liquid phase to obtain fatty acids. Results of investigation of various factors are charted and tabulated. They show a maximum yield (55%) at 115°-120° with 0.2 permanganate and 8-hr. reaction time. The various acids separated and identified, ranged from CH2O to the C20 acid, distribution being fairly uniform. |