129. -------------. [BAHR, H. A.] [Reduction of Carbonic Acid.] Ges. Abhandl. Kenntnis Kohle, vol. 8, 1929, pp. 219-224; Chem. Zentralb., 1930, I, p. 185; Chem. Abs., vol. 24, 1930, p. 5207. Reduction of CO2 according to CO2+H2=CO+H2O, which up to the present has been investigated only at relatively high temperatures, can be carried out also at moderate temperature if the proper catalysts are employed. With metallic Cu the reaction is noticeable at 200°. With the employment of Cu·Cr2O3Fe·Cu, Fe·CO and Co·Cu·Zu as contact materials with temperatures between 200° and 450° and with mixtures of CO2 and H2 in the ratio 1:1 and 1:3, respectively, the CO quantities obtained were up to 16%. With a slow current of the gas mixture, reduction of CO to CH4 occurred, especially when contacts containing Co were employed. |