65. APIN, A., LEIPUNSKII, O., AND REINOV, N. [Decomposition of Methanol Under High Pressures.] Jour. Gen. Chem. (U.S.S.R.), vol. 10, 1940, pp. 863-865; Chem. Abs., vol. 35, 1941, p. 2469. With the aim to investigate the influence of high pressures on simple reactions of organic compounds, the behavior of MeOH has been investigated. The decomposition of MeOH was studied at 350° under pressures of 600, 2,000, 6,000, and 8,000 atm. The reaction products were Me2O, CH4, CO2, and H2. Unsaturated hydrocarbons could not be detected. The amount of Me2O increased with increasing pressure and decreased at a given pressure with prolonged reaction time. CO and H2 were formed in small amounts and CH4 in large amounts when high pressures were applied. The amount of CO and H2 decreased with prolonged reaction time while the amount of CH4 increased. The reaction vessel used consisted of nonrusting steel containing about 8% CrO3 which possibly acts as a catalyst. A series of reactions is given that the decomposition reaction is assumed to follow. APPEL, E. G. See abs. 99. APPEL, H. See abs. 1710. APPEL, H., BÖHM, H., KEIL, W., AND SCHILLER, G. Fat From Fat Acids With Odd Numbers of Carbon Atoms. IV. See abs. 1713. ---------------. Fat From Fat Acids With Odd Numbers of Carbon Atoms. VII. Preliminary Communication Concerning Properties. Stability, Physiology, and Toxicology of Synthetic Fats From Paraffin Fat Acids. See abs. 1717. APPEL, H., BERGER, G., BÖHM, H., KEIL, W., AND SCHILLER, G. Fats From Fat Acids With Uneven Numbers of Carbon Atoms. II. See abs. 1711. |