62. ANTHEAUME, J., DECARRIČRE, E., AND RČANT, R. [Physicochemical Study of the Iron Catalyst Used in the Synthesis of Liquid Hydrocarbons.] Chim. et ind., Special No., April 1934, pp. 421-423; Compt. rend., vol. 196, 1933, pp. 1889-1890; Brennstoff-Chem., vol. 15, 1934, p. 413; Chem. Abs., vol. 28, 1934, p. 5935. From investigations by the thermomagnetic-analysis method of Chaudron and coworkers for the study of metallic oxides (Forestier and Chaudron, abs. 1054), it is concluded that catalytic conversion does not take place in presence of either Fe2O3 alone or of Fe3O4 alone. In every case in which catalytic activity is manifested, Fe3O4 is present, and the activity increases with the fineness of the crystalline structure. The authors admit that, with their catalysts, the production of higher hydrocarbons by hydrogenation takes place in the presence of complex solid solutions. |