55. ANDREWS, G. W. Water-Gas Equilibrium in Hydrocarbon Flames. Jour. Chem. Soc., vol. 105, 1914, pp. 444-456; Jour. Soc. Chem. Ind. (London), vol. 33, 1914, p. 303; Chem. Abs., vol. 8, 1914, p. 1659. Andrews concludes that the explosive combustion of numerous hydrocarbon-O2 mixtures under widely differing conditions of incomplete combustion give rise to products that at least approximately conform to the requirements of the water-gas equilibrium with a value of 4 for the thermodynamic constant, and the value is not greatly altered even when large quantities of C are separated or considerable % of CH4 is found in the ultimate products. |