27. ALLNER, W. [Bunsen Flame.] Jour. Gasbeleucht., vol. 48, 1905, pp. 1035-1040; Jour. Chem. Soc., vol. 90, (2), 1906, pp. 441-442. In the relatively cold flames formed by burning mixtures of CO2 and H2, or of CO and H2, a state of equilibrium is not attained. In the flames of mixtures of CH4 and H2, CH4, H2, and CO2, C6H6 and H2, and C6H6, H2, and CO2, the equilibrium K = [(H2O) (CO)]/[(CO2) (H2)], corresponding with the temperature is established. The effect of temperature on the equilibrium is discussed, and the values of the constant in the equation log K = -1/0.4343.R?q/T2.dt+constant are calculated from the different values of K and the effect of temperature on the specific heats of the gases. |