5. ADKINS, H., AND NISSEN, B. H. Selective Activation of Alumina. II. Reactions of Formic Acid at the Surface of Alumina. Jour. Am. Chem. Soc., vol. 45, 1923, pp. 809-815; Chem. Abs., vol. 17, 1923, p. 2104. Effects of Al2O3 catalysts prepared in different ways on the decomposition of HCO2H were studied. The amounts of H2 and CO2 formed agreed very closely, so that decomposition occurs almost entirely according to the reactions HCO2H=CO2+H2 and HCO2H=CO+H2O and to no considerable extent according to the equation 2 HCO2H=HCHO+CO2+H2O. It is concluded that the distances separating the molecules of Al2O3, as determined by the method of preparation, were the important factors in defining the activity and selectivity of the catalyst |