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Optimization of Coal Gasification Processes.
R&D Report No. 66 Wen, C. Y. West Virginia University Table of Contents Summary S-1 I. Introduction 1. Classification of Coal Gasification Systems I-3 2. Methodology of Systems Analysis and Optimization I-5 II. Cost Information 1. Equipment Cost II-2 2. Cost of Direct Material and Utility II-4 3. Raw Material Cost II-5 III. Coal Preparation and Pretreatment 1. Crude Preparation of Coal III-1 2. Preparation of Coal III-1 3. Pretreatment III-9 4. Feeding Apparatus III-11 5. Summary of Preparation and Pretreatment of Coal III-12 IV. Gasification 1. Alternative Coal Gasification Processes IV-2 2. Material and Energy Balance IV-22 3. Effective Utilization of Coal in the Integrated Pipeline Gas Production Plant IV-38 4. Kinetics of Gasification Reactions and Reactor Design IV-72 5. Optimization of Gasification Phase Equipment Costs IV-94 V. Shift Conversion 1. Thermodynamic and Reaction Kinetics V-5 2. Reactor Performance Equation V-16 3. Optimization V-18 4. Kinetics of Gasification Reactions and Reactor Design IV-72 5. Optimization of Gasification Phase Equipment Costs IV-94 VI. Gas Purification 1. Gas Purification Processes VI-1 2. Flow System of Hot Potash and Amine Processes for Absorption of CO2 and H2S VI-9 3. Basic Thermodynamic Data VI-15 4. Reaction Kinetics and Thermodynamics VI-31 5. Flooding Velocity, Diameter of Tower and Pressure Drop in Packed Tower VI-39 6. Heat and Mass Transfer Coefficients VI-41 7. Material and Heat Balances VI-50 8. Heat Exchanger Design VI-75 9. Energy-Recovery System VI-82 10. Removal of Sulfur Compounds by Solid Adsorbents VI-89 11. Optimization of CO2 and H2S Removal Processes VI-92 12. Removal of Benzene by Activated Carbon Process VI-111 13. Conclusion and Recommendation for Further Investigation VI-120 VII. Methanation 1. Reaction Kinetics VII-5 2. Reactor Performance VII-16 3. Process Optimization of Heat Exchangers VII-18 4. Heat Extraction System VII-34 5. Cold Quench System VII-55 6. Recycle System VII-78 7. Discussion VII-88 8. Conclusion VII-102 9. Recommendation VII-105 10. Supplement VII-114 VIII. Overall Plant Optimization 1. Description of Gas Manufacturing Processes VIII-1 2. Summary of Equipment Costs VIII-14 3. Optimization and Gas Price Calculations VIII-17 4. Results of Overall Plant Optimization VIII-23 5. Conclusions and Recommendations VIII-64 Appendices A Fluidized Bed and Fixed Bed B Computer Programs |