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Technology Development for Cobalt F-T Catalysts Quarterly Technical Progress Report No. 9 Covering the Period October 1, 1994 to December 31, 1994 - 1995

Tischer, Richard E.
Singleton, Alan H.

U.S. Department of Energy
Energy International Corporation

Table of Contents 132kb

Report 940kb

Executive Summary iv

I

Introduction and Background 1

II

Project Description 1

III

Objectives 33

IV

Summary of Work Accomplished This Quarter 4

V

Detailed Description of Technical Progress 5
 

A

Task 1:  Catalyst Development 5
 

a

Technology Assessment 5

b

Catalyst Formulation 5

c

Catalyst Pretreatment 6

d

Catalyst Characterization 7

B

Task 2:  Catalyst Testing 8
 

a

Fixed Bed Reactor 8

b

Slurry Bubble Column Reactor 9

VI

Plans for the Next Reporting Period 15

VII

Assessment of Prospects for Future Progress 17

VIII

Appendices 45
 

A

Co Catalyst Formulations 2603kb

B

Fixed Bed Reaction Data 1992kb

C

Chronology of Runs in Slurry Bubble Column Reactors 324kb

D

Slurry Bubble Column Data 1272kb

List of Tables

Tables 1833kb

1 List of Co-based F-T Catalysts Formulated 18
2 List of Water-Gas-Shift Catalysts and F-T Catalysts with WGS Function 23
3 Summary of Physical Properties 24
4 H2 Chemisorption and TPR Results 27
5 Summary of Fixed Bed Reaction Results 31
6 Comparison of Conversion and Selectivity of Methane Reduction Catalysts at Startup Conditions in M4-SBCR 35
7 Summary of M3-SBCR Run #30 Results 36
8 Summary of M4-SBCR Run #24 Results 37
9 Summary of M3-SBCR Run #33 Results 38
10 Summary of M4-SBCR Run #26 Results 39
11 Comparison of Conversion and Selectivity Calsicat-Produced Catalysts at Startup Conditions in M4 & M3 40
12 Comparison of Conversion and Selectivityof Methane Reduction Catalysts at Startup Conditions in M3 41
13 SBCR Catalyst Extractions 42