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Liquid Phase Methanol LaPorte PDU: Modification, Operation, and Support Studies.
Task 3.4, Adsorbent Evaluation for Removal of Catalyst Poisons from Synthesis Gas - 1990

Air Products and Chemicals, Inc.

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Table of Contents

Introduction

1

Objective

2

Summary and Conclusions

4

Patent Situation

8

Safety

9

Future Program

9

Acknowledgement

9

Experimental Apparatus and Procedures

10

Results and Discussion

15
 

Adsorption of of Fe(CO)5

15

Adsorption of Ni(CO)4

39

Adsorption of COS

47

Adsorption of H2S

51

Adsorption of HCl

59

Pilot Unit Design

67

References

71

Appendix A

72

Appendix B

86

Appendix C

90