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Mechanistic Studies Related to the Metal Catalyzed Reductions
of Carbon Monoxide to Hydrocarbons.
Progress Report, April 1, 1978 to March 31, 1979
Casey, Charles P.
University of Wisconsin
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Table of Contents
| Abstract |
3 |
|
I |
Metal Formyl Complexes |
4 |
| |
A |
Comparison of Metal Formyl and Metal Acyl Compounds |
4 |
| |
1 |
Structure |
4 |
| 2 |
Kinetic Stability of Metal Formyl and Metal Acetyl
Compounds |
6 |
| 3 |
Relative Thermodynamic Stability of Metal Formyl and
Metal Acetyl Compounds |
9 |
| B |
Chemical Reactivity of
Metal Formyl Compounds |
10 |
| |
1 |
Hydride Donation Reactions |
10 |
| 2 |
Synthesis of a Neutral Metal Formyl Compound |
11 |
| References |
14 |
| 