Title Page |
1 |
Disclaimer |
2 |
Abstract |
3 |
Table of Contents |
4 |
Executive Summary |
5 |
Objectives and Specific Tasks |
6 |
Technical Activities and Accomplishments |
7 |
Immediate Next Steps and Research Plan |
8 |
Appendix A: |
9 |
1. |
Experimental Details |
9 |
1.1 |
Synthesis of Precursors and Catalysts |
9 |
1.2 |
Fischer-Tropsch Synthesis Reaction and Product Selectivity |
10 |
2. |
Results and Discussion |
10 |
2.1 |
Prepared Catalysts and BET Surface Area |
10 |
2.2 |
Fischer-Tropsch Synthesis on Iron-Based Catalysts with Hydrogen-poor Synthesis gas |
11 |
2.2.1 |
Effect of promoter order addition on Fischer-Tropsch Synthesis Rates and Selectivities |
12 |
2.2.2 |
Catalytic performance of Fe-Zn-Cu3-K6 in Fischer-Tropsch Synthesis |
12 |
2.3 |
Structure Evolution and Site Requirements in Fe-Catalyzed Fischer-Tropsch Synthesis |
13 |
2.3.1 |
Catalytic behavior of Fe-based catalysts during isothermal activation |
13 |
2.3.2 |
Structure evolution during the activation process |
14 |
2.3.2.1 |
In situ the structure and products during reactions on Fe-ZN-Cu3-K6 with synthesis gas |
15 |
2.3.2.2 |
In situ structure and product evolutions during the catalytic activation process |
17 |
2.4 |
Kinetic Study of the Fischer-Tropsch Synthesis with Iron-based Catalyst |
21 |
2.4.1 |
Influence of H2 partial pressure on reaction rates and product selectivity |
22 |
2.4.2 |
Influence of CO2 partial pressure on reaction rates and Product selectivity |
23 |
2.4.3 |
Mechanism and kinetics of hydrocarbon formation |
26 |
2.5 |
Bimetallic Colloids for Fischer-Tropsch Synthesis Catalysts |
27 |
2.5.1 |
CoRu Bimetallic Colloid Preparation and Support on ZrO2/SiO2 |
28 |
Appendix B: |
29 |
1. |
Publications |
29 |
2. |
Presentations and Abstracts |
29 |