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Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen Table of Contents

C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen.  Semi-Annual six-month report.  Research Conducted October 1, 2004-March 31, 2005.

Huffman, Gerald P.

University of Kentucky

In this pdf format, this document has 85 pages and is 1.85MB.

Table of Contents

Abstract

1

Executive Summary

2

Chain Initiation of Fischer-Tropsch with Acetylene Incorporation

6

SBA-15 Supported Cobalt and Iron Catalysts for Fischer-Tropsch Synthesis

10

Gas-Phase Incorporation of Organometallic Compounds within Aerogels for Synthesis of Fischer-Tropsch and Water Gas Shift Catalysts

15

Stability and Structure of Cobalt Catalytic Systems in Fischer-Tropsch Synthesis:  Supercritical Fluid Media Versus Conventional Gas-Phase Media.

20

Development of Molybdenum-Promoted Catalysts Supported on Activated Carbon for Diesel Fuel Synthesis

26

New Catalysts for the Production of Chemicals, Light olefins and Hydrogen via C-1 Chemistry

36

What C-13 chemical shift tensors can tell us about metal ligand interactions in catalysts

44

Science behind Catalysis in C1 Reactions: Catalyst characterization and determination of Active Species

46

Mossbauer, XAFS and TEM Analysis of Fe-M0 WGS catalysts

52

Hydrogen production from Methanol in Supercritical Water

66

Coproduction of Hydrogen and Chemicals by Decomposition of Methanol

71

Hydrogen by Catalytic Reforming of Glycols

75

Hydrogen Production by Catalytic Methane Decomposition using a Semi-Continuous Fluidized-Bed Reactor

78