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Site Activities of Zeolite-Support RU for CO Hydrogenation.  Final Report - October 1983

Goodwin, James G. , Jr.

University of Pittsburgh

In this pdf format, Part , 1 - 119 pages is 4.37MB.

In this pdf format, Part 2, Pages 120 - 218 is 3.52MB.

 

Table of Contents

Part 1

I.

Objective and Scope of Work

1

II.

Summary of Accomplishments

2

III.

Articles and Presentations

4

IV.

Results and Discussions

7

 

Chemisorption Characteristics

 

 

Reversible Chemisorption on Highly Dispersed Ru Catalysts

9

Particle Rise Dependence for CO Chemisorption On Supported Ru Catalysts

27

Hydrogen Chemisorption Suppression in Ru-Zeolite Catalysts

37

Electronic State of Ru

 

 

The Electronic Properties of Ru in Y Zeolites as Determined by ESCA

56

Hydrogenolysis Properties of NaY-Supported Ru

 

 

Structure and Properties of Zeolite-Supported Ru3(CO)12 Catalysts

87

Characterization of Ru Zeolite Catalysts By a Hydrogenolysis Test Reaction Network

105

Part 2
 

Fischer-Tropsch Synthesis

 

 

The Influence of the Support on K Promotion Of Ru for the F-T Synthesis

128

Effect of Preparation Method on the Catalytic Properties of Zeolite-Supported Ru in the F-T Synthesis

135

F-T Synthesis over Zeolite-Supported Ru Catalysts Derived from Ru3(CO)12

171

Support Effects on CO Hydrogenation over Ru/Zeolite Catalysts

190