PATENT

3634.  STEINSCHLAEGER, M., AND OVERSEAS FINANCE & COMMERCE, LTD.  Synthetic Production of Hydrocarbon Oils.  British Patent 575,378, Feb. 15, 1946; appl. filed July 5, 1939.  British Abs., I, B, 1946, p. 197.

Motor fuel and lubricating oil, both of high olefin content, are synthesized by passing blue water gas over a catalyst of Co activated with ThO2 160°-250°, separating the olefinic oils produced, washing the CO2 from the residual gas (0.4 vol.), and mixing the washed gas with a gas containing H2 and CH4 produced by heating in a current of H2 the waxy deposit formed on the Fischer-Tropsch catalyst and a H2-rich gas mixture produced by treating coal gas with steam on a Ni-Mo sulfide catalyst or by treating blue water gas with steam on a Co-ThO2 catalyst to yield a synthesis gas containing CO, 29%: H2, 58%:CH4, 5%: and CO2+N2, 8%.  The synthesis gas when passed over a Co, a Ni or an Fe catalyst, which may be activated by ThO2 or an Fe catalyst, which may be activated by ThO2 or Cu, 160°-250° yields olefinic liquid products 140 gm. per m.3 .  Products of still higher olefin content are obtained by using a synthesis gas containing CO 34%+H2 51% prepared by suitable adjustment of the constituents mentioned.