PATENTS

2001. ------. [LARSON, A. T.] (E. I. du Pont de Nemours & Co.). Carboxylic Acids. United States Patent 2,448,375, Aug. 31, 1948. Chem. Abs., vol. 43, 1949, p. 670.

Aliphatic carboxylic acids, such as EtCO2H, are prepared by the reaction of steam, CO, and an olefinic hydrocarbon at 500-1,500 atm. in the presence of a catalyst, such as NiCO or CoCO and active C, at 200°-400°.