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Return to Abstracts of Literature 1750-1999

Literature Abstracts

 1853.    ---------------.  [FUJIMURA, K. AND TSUNEOKA, S.]  Synthesis of Benzine From Carbon Monoxide and Hydrogen under Ordinary Pressure.  XVII.  The General Properties and Chemical Composition of the Reaction Products.  Jour. Soc. Chem. Ind. (Japan), vol. 37, suppl., 1934, pp. 395-400; Sci. Papers Inst. Phys. Chem. Research (Tokyo), vol. 24, 1934, pp. 79-92; Brennstoff-Chem., vol. 15, 1934, p. 412; British Chem. Abs., 1934, B, p. 662; Chem. Abs., vol. 28, 1934, p. 4655.

        Products of the reaction were gases, oils and an aqueous solution.  Composition of the gases varied widely.  With a Co catalyst there was a little CO2 and some hydrocarbons together with unchanged CO and H2 but with Ni catalysts the hydrocarbons varied 6-35%.  80% of the oils distilled below 200° and the normal paraffins from C5 to C11 were identified.  The use of Ni catalysts gave over 90% saturated hydrocarbons while Co gave up to 57% olefins.  No aromatic hydrocarbons or naphthenes could be detected.  The higher the boiling point of a fraction the less olefin it contained.  Investigation of the aqueous solution showed small amounts of aldehydes, alcohols, acids, and ketones.