112. ----------------. [Chemical Equilibrium Between Methanol, Carbon Monoxide and Hydrogen.] Ann. combust, liquides, vol. 5, 1930, pp. 454-461; Chem. Abs., vol. 25, 1931, p. 635.

112. ----------------. [AUDIBERT, E., AND RAINEAU, A.] [Chemical Equilibrium Between Methanol, Carbon Monoxide and Hydrogen.] Ann. combust, liquides, vol. 5, 1930, pp. 454-461; Chem. Abs., vol. 25, 1931, p. 635.

With enough time of contact the following reactions take place: CO+2H₂=CH₂OH; 2CO+2H₂=CO₂+CH₄; and CO+3H₂=CH₄+H₂O. The reaction constant for the first reaction under the above conditions can be determined, and from the experiments the following relation is found:

6806

log K = -35.38+--------+7.22 log T.

AVERBUKH, B. D. See abs. 564, 566.